@unpublished{pittir10754,
           month = {January},
           title = {Studies of Memory of Chirality in Amide Radical Cyclizations },
          author = {ANIRUDDHA SASMAL},
            year = {2012},
        keywords = {Memory of Chirality, N-tert-butyl substituted amides, 1,4-phenyl radical migration},
             url = {http://d-scholarship-dev.library.pitt.edu/10754/},
        abstract = {Radical cyclizations of amide substrates were performed to establish the Memory of Chirality (MOC). Amides with N-tert-butyl substituent due to their hindered rotation around C-N bond gives cyclized product with retention of configuration upon radical reaction condition. Chiral GC analysis and theoretical optical rotation calculation were used to verify the MOC. An unexpected 1,4-phenyl radical migration was also observed during the radical reaction of N-benzyl substituted amides.}
}