?url_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rft.relation=http%3A%2F%2Fd-scholarship-dev.library.pitt.edu%2F10687%2F&rft.title=Studies+of+Memory+of+Chirality+in+Amide+Radical+Cyclizations+&rft.creator=SASMAL%2C+ANIRUDDHA&rft.description=Radical+cyclization+of+amide+substrates+was+performed+to+establish+the+Memory+of+Chirality+(MOC).+Amides+with+N-tert-butyl+substituent+due+to+their+hindered+rotation+around+C-N+bond+gives+cyclized+product+with+retention+of+configuration+upon+radical+reaction+condition.+Chiral+GC+analysis+and+theoretical+optical+rotation+calculation+were+used+to+verify+the+MOC.+An+unexpected+1%2C4-phenyl+radical+migration+was+also+observed+during+the+radical+reaction+of+N-benzyl+substituted+amides.&rft.date=2012-01-18&rft.type=University+of+Pittsburgh+ETD&rft.type=PeerReviewed&rft.format=application%2Fpdf&rft.language=en&rft.identifier=http%3A%2F%2Fd-scholarship-dev.library.pitt.edu%2F10687%2F1%2FETD_2.pdf&rft.identifier=++SASMAL%2C+ANIRUDDHA++(2012)+Studies+of+Memory+of+Chirality+in+Amide+Radical+Cyclizations.++Master's+Thesis%2C+University+of+Pittsburgh.++++(Unpublished)++