Synthesis and Reactivity of Dioxycarbenium Ions from Epoxy Esters and Cationic Zirconium Complexes

Wipf, P and Xu, W (1993) Synthesis and Reactivity of Dioxycarbenium Ions from Epoxy Esters and Cationic Zirconium Complexes. Journal of Organic Chemistry, 58 (22). 5880 - 5882. ISSN 0022-3263

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Abstract

Rearrangement of epoxy esters in the presence of Cp2Zr(R)+ or Cp2Zr(Cl)+ results in synthetically useful dioxycarbenium intermediates. Acetals, ortho esters, and tetrahydrofurans are prepared by ligand transfer from zirconium, intramolecular trapping, or further rearrangement reactions. © 1993, American Chemical Society. All rights reserved.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Xu, W
Date:	1 January 1993
Date Type:	Publication
Journal or Publication Title:	Journal of Organic Chemistry
Volume:	58
Number:	22
Page Range:	5880 - 5882
DOI or Unique Handle:	10.1021/jo00074a006
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0022-3263
Date Deposited:	06 Oct 2015 14:56
Last Modified:	12 Jun 2021 22:55
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/25724

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