Goldstein, DM and Wipf, P
(1996)
Studies Toward the Synthesis of Stemona Alkaloids; A Short Synthesis of the Tricydic Core of Tuberostemonines.
Tetrahedron Letters, 37 (6).
739 - 742.
ISSN 0040-4039
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Abstract
The tricyclic hydroindole core system of the Stemona alkaloids was prepared in 9 steps from N-Aloc-tyramine. The synthesis features oxidation of tyramine with hypervalent iodine followed by intramolecular conjugate addition and Mitsunobu cyclization of an ammo-alcohol as the key steps.
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