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Additions of electrophilic radicals to electron rich alkenes by the atom transfer method. Surmounting potentially reversible radical atom transfer reactions by irreversible ionic reactions

Curran, DP and Ko, SB (1998) Additions of electrophilic radicals to electron rich alkenes by the atom transfer method. Surmounting potentially reversible radical atom transfer reactions by irreversible ionic reactions. Tetrahedron Letters, 39 (37). 6629 - 6632. ISSN 0040-4039

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Abstract

Conditions have been developed for the atom transfer radical addition reaction of bromoesters to enolethers. The putative intermediate haloethers are allowed to ionize and the resulting cations are trapped by addition or elimination reactions.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Curran, DPcurran@pitt.eduCURRAN
Ko, SB
Date: 10 September 1998
Date Type: Publication
Journal or Publication Title: Tetrahedron Letters
Volume: 39
Number: 37
Page Range: 6629 - 6632
DOI or Unique Handle: 10.1016/s0040-4039(98)01405-1
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0040-4039
Date Deposited: 07 Aug 2014 17:01
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship-dev.library.pitt.edu/id/eprint/22641

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