Curran, DP and Liu, W
(1999)
Radical cyclization/fragmentation reactions of dicyanocyclopropanes to enaminonitriles. A radical alternative to the Thorpe-Ziegler reaction.
Synlett (1).
117 - 119.
ISSN 0936-5214
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Abstract
Radical cyclizations to dicyanocyclopropanes provide cyclic enaminonitriles by a series of radical reactions that features radical cyclization to a nitrile and cyclopropane cleavage. The direction of cyclopropane cleavage - and hence the ring size of the final product - depends on the nature of the ring formed in the initial cyclization to the nitrile.
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