'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions

Curran, DP and Luo, Z and Degenkolb, P (1998) 'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions. Bioorganic and Medicinal Chemistry Letters, 8 (17). 2403 - 2408. ISSN 0960-894X

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Abstract

A new generation of propylene-spaced fluorous allyltin reagents [(Rf(CH2)3)3SnCH2CH=CH2] is described. These succeed in radical allylations where their lower homologs (ethylene-spaced) fail, and they provide improved performance in transition metal catalyzed allylations. The reagents and byproducts are readily separated by simple fluorous-organic liquid-liquid or solid-liquid extractions.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Curran, DP curran@pitt.edu CURRAN Luo, Z Degenkolb, P
Date:	8 September 1998
Date Type:	Publication
Journal or Publication Title:	Bioorganic and Medicinal Chemistry Letters
Volume:	8
Number:	17
Page Range:	2403 - 2408
DOI or Unique Handle:	10.1016/s0960-894x(98)00435-1
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0960-894X
MeSH Headings:	Aldehydes--chemical synthesis; Aldehydes--chemistry; Alkenes; Catalysis; Fluorides; Indicators and Reagents; Metals; Organotin Compounds--chemical synthesis; Organotin Compounds--chemistry; Structure-Activity Relationship
PubMed ID:	9873550
Date Deposited:	28 Jul 2014 19:11
Last Modified:	12 Jun 2021 22:56
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/22506

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