Formation of cyclopropanes by homolytic substitution reactions of 3- iodopropyl radicals: Preparative and rate studies

Curran, DP and Gabarda, AE (1999) Formation of cyclopropanes by homolytic substitution reactions of 3- iodopropyl radicals: Preparative and rate studies. Tetrahedron, 55 (11). 3327 - 3336. ISSN 0040-4020

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Abstract

Reduction of 2-substituted 1,3-diiodopropane derivatives with tin hydride provides substituted cyclopropanes. The reaction occurs through a homolytic substitution of the 3-iodopropyl radical, which has a rate constant of about 5 x 105 s-1 at 80°C.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Curran, DP curran@pitt.edu CURRAN Gabarda, AE
Date:	1 March 1999
Date Type:	Publication
Journal or Publication Title:	Tetrahedron
Volume:	55
Number:	11
Page Range:	3327 - 3336
DOI or Unique Handle:	10.1016/s0040-4020(98)01144-2
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0040-4020
Date Deposited:	22 Sep 2014 20:31
Last Modified:	12 Jun 2021 22:56
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/22458

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