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N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: A mechanistic investigation

Gatineau, D and Zhao, Q and Curran, DP and Malacria, M and Lacôte, E and Fensterbank, L and Goddard, JP (2013) N-Heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: A mechanistic investigation. Dalton Transactions, 42 (20). 7458 - 7462. ISSN 1477-9226

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Abstract

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC. © 2013 The Royal Society of Chemistry.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Gatineau, D
Zhao, Q
Curran, DPcurran@pitt.eduCURRAN
Malacria, M
Lacôte, E
Fensterbank, L
Goddard, JP
Date: 28 May 2013
Date Type: Publication
Journal or Publication Title: Dalton Transactions
Volume: 42
Number: 20
Page Range: 7458 - 7462
DOI or Unique Handle: 10.1039/c3dt32983f
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 1477-9226
PubMed ID: 23459715
Date Deposited: 05 Mar 2014 21:27
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship-dev.library.pitt.edu/id/eprint/20674

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