Preparation of a fluorous chiral BINOL derivative and application to an asymmetric protonation reaction

Nakamura, Y and Takeuchi, S and Ohgo, Y and Curran, DP (2000) Preparation of a fluorous chiral BINOL derivative and application to an asymmetric protonation reaction. Tetrahedron, 56 (3). 351 - 356. ISSN 0040-4020

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Abstract

Fluorous Chiral Proton Source (R,S)-FDHPEB resulted in a higher enantioselectivity (95% ee) than that of the original nonfluorous (R,S)-DHPEB (87% ee) in an enantioselective protonation of a samarium enolate. (R,S)- FDHPEB was easily recovered by a simple filtration through a fluorous reverse phase silica gel and was recyclable. (C) 2000 Elsevier Science Ltd.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Nakamura, Y Takeuchi, S Ohgo, Y Curran, DP curran@pitt.edu CURRAN
Date:	14 January 2000
Date Type:	Publication
Journal or Publication Title:	Tetrahedron
Volume:	56
Number:	3
Page Range:	351 - 356
DOI or Unique Handle:	10.1016/s0040-4020(99)01004-2
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0040-4020
Date Deposited:	21 Feb 2014 21:05
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/20618

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