Fluorous reverse phase silica gel. A new tool for preparative separations in synthetic organic and organofluorine chemistry

Curran, DP (2001) Fluorous reverse phase silica gel. A new tool for preparative separations in synthetic organic and organofluorine chemistry. Synlett (9). 1488 - 1496. ISSN 0936-5214

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Abstract

Fluorous reverse phase silica gel, or silica gel with a fluorocarbon bonded phase, can be readily prepared by standard techniques, but shows unusual separation features. This silica gel separates primarily by fluorine content. Uses of fluorous reverse phase silica gel in both synthetic organic chemistry and organofluorine chemistry are introduced. Solid phase extraction can be used to separate fluorous or fluorous-tagged compounds from organic compounds. Fluorous chromatography can be used to purify mixtures of compounds with differing fluorine content as well as for "demixing" in the new technique of fluorous mixture synthesis.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Curran, DP curran@pitt.edu CURRAN
Date:	1 January 2001
Date Type:	Publication
Journal or Publication Title:	Synlett
Number:	9
Page Range:	1488 - 1496
DOI or Unique Handle:	10.1055/s-2001-16800
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0936-5214
Date Deposited:	13 Feb 2014 19:28
Last Modified:	19 Jul 2020 11:56
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/20537

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