Link to the University of Pittsburgh Homepage
Link to the University Library System Homepage Link to the Contact Us Form
D-Scholarship @ Pitt Banner and Links to Homepage

Recyclable fluorous chiral ligands and catalysts: Asymmetric addition of diethylzinc to aromatic aldehydes catalyzed by fluorous BINOL-Ti complexes

Nakamura, Y and Takeuchi, S and Okumura, K and Ohgo, Y and Curran, DP (2002) Recyclable fluorous chiral ligands and catalysts: Asymmetric addition of diethylzinc to aromatic aldehydes catalyzed by fluorous BINOL-Ti complexes. Tetrahedron, 58 (20). 3963 - 3969. ISSN 0040-4020

[img] Plain Text (licence)
Available under License : See the attached license file.
Download (1kB)

Abstract

Fluorous chiral BINOLs were prepared and used as the ligands for the titanium catalyzed asymmetric addition of Et2Zn to aromatic aldehydes. Consecutive reactions were examined by utilizing fluorous-organic biphase and fluorous solid phase extraction techniques. Enantioselectivities were similar in consecutive reactions and were close to that attained in the non-fluorous system. The solid phase extraction method also enabled us to perform a simultaneous screening procedure. © 2002 Elsevier Science Ltd. All rights reserved.

Share

Citation/Export:
Social Networking:
Share |

Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Nakamura, Y
Takeuchi, S
Okumura, K
Ohgo, Y
Curran, DPcurran@pitt.eduCURRAN
Date: 13 May 2002
Date Type: Publication
Journal or Publication Title: Tetrahedron
Volume: 58
Number: 20
Page Range: 3963 - 3969
DOI or Unique Handle: 10.1016/s0040-4020(02)00245-4
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0040-4020
Date Deposited: 12 Feb 2014 23:42
Last Modified: 12 Jun 2021 23:55
URI: http://d-scholarship-dev.library.pitt.edu/id/eprint/20491

Metrics

Monthly Views for the past 3 years

Plum Analytics

Altmetric.com

Actions (login required)

View Item View Item