Phase-vanishing reactions that use fluorous media as a phase screen. Facile, controlled bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide

Ryu, I and Matsubara, H and Yasuda, S and Nakamura, H and Curran, DP (2002) Phase-vanishing reactions that use fluorous media as a phase screen. Facile, controlled bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide. Journal of the American Chemical Society, 124 (44). 12946 - 12947. ISSN 0002-7863

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Abstract

In fluorous triphasic reactions, such as bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide, the middle fluorous phase acts as a liquid membrane permitting passive transport of the reagents at the bottom to the top layer involving the substrates, thereby regulating the reactions. Copyright © 2002 American Chemical Society.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Ryu, I Matsubara, H Yasuda, S Nakamura, H Curran, DP curran@pitt.edu CURRAN
Date:	6 November 2002
Date Type:	Publication
Journal or Publication Title:	Journal of the American Chemical Society
Volume:	124
Number:	44
Page Range:	12946 - 12947
DOI or Unique Handle:	10.1021/ja027965y
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0002-7863
MeSH Headings:	Alkenes--chemistry; Alkylation; Boron Compounds--chemistry; Bromine--chemistry; Ethers--chemistry; Fluorocarbons--chemistry; Hydrocarbons, Brominated--chemical synthesis
PubMed ID:	12405811
Date Deposited:	07 Feb 2014 00:02
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/20487

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