Water-Accelerated Tandem Claisen Rearrangement-Catalytic Asymmetric Carboalumination

Wipf, P and Ribe, S (2001) Water-Accelerated Tandem Claisen Rearrangement-Catalytic Asymmetric Carboalumination. Organic Letters, 3 (10). 1503 - 1505. ISSN 1523-7060

Plain Text (licence) Available under License : See the attached license file. Download (1kB)

Abstract

matrix presented The addition of stoichiometric quantities of water accelerates both the trimethylaluminum-mediated aromatic Claisen reaction and the chiral zirconocene-catalyzed asymmetric carboalumination of terminal alkenes. The two reactions occur in a tandem sequence resulting in the selective formation of two new C-C and one C-O bond after oxidative quench of the intermediate trialkylalane.

---

Share

Citation/Export:	Select format... Citation - Text Citation - HTML Endnote BibTex Dublin Core OpenURL MARC (ISO 2709) METS MODS EP3 XML Reference Manager Refer
Social Networking:	Share |

---

Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Ribe, S
Date:	17 May 2001
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	3
Number:	10
Page Range:	1503 - 1505
DOI or Unique Handle:	10.1021/ol015816z
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
PubMed ID:	11388852
Date Deposited:	13 Feb 2014 18:57
Last Modified:	02 Feb 2019 15:57
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/20483

---

Metrics

Monthly Views for the past 3 years

Plum Analytics

Altmetric.com

---

Actions (login required)

View Item