A New Ligand Scaffold for Catalytic Asymmetric Alkylzinc Additions to Aldehydes

Wipf, P and Wang, X (2002) A New Ligand Scaffold for Catalytic Asymmetric Alkylzinc Additions to Aldehydes. Organic Letters, 4 (7). 1197 - 1199. ISSN 1523-7060

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Abstract

matrix presented 1,3-Azole derivatives of 2-aminocyclohexanecarboxylic acid represent a new class of bidentate ligands for metal-mediated catalytic asymmetric synthesis. N-[2-(4-Isopropyl-4,5-dihydrooxazol-2-yl)cyclohexyl]methanesulfonamide (6) is particularly well suited for the addition of alkylzinc reagents to aliphatic aldehydes in high enantiomeric excess.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Wang, X
Date:	4 April 2002
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	4
Number:	7
Page Range:	1197 - 1199
DOI or Unique Handle:	10.1021/ol025600c
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
Other ID:	10.1021/ol025600c
PubMed ID:	11922817
Date Deposited:	12 Feb 2014 23:42
Last Modified:	05 Feb 2019 16:55
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/20456

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