Silver(I)-catalyzed addition of zirconocenes to glycal epoxides. A new synthesis of α-c-Glycosides

Wipf, P and Pierce, JG and Zhuang, N (2005) Silver(I)-catalyzed addition of zirconocenes to glycal epoxides. A new synthesis of α-c-Glycosides. Organic Letters, 7 (3). 483 - 485. ISSN 1523-7060

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Abstract

(Chemical Equation Presented) Hydrozirconation of terminal alkynes, followed by AgClO4-catalyzed in situ addition of the resultant alkenylzirconocenes to 1,2-anhydrosugars (glycal epoxides) leads to α-C-glycosides in moderate to high yields.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wipf, P pwipf@pitt.edu PWIPF Pierce, JG Zhuang, N
Date:	3 February 2005
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	7
Number:	3
Page Range:	483 - 485
DOI or Unique Handle:	10.1021/ol0475414
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
MeSH Headings:	Catalysis; Epoxy Compounds--chemical synthesis; Glycosides--chemical synthesis; Indicators and Reagents; Molecular Conformation; Organometallic Compounds--chemistry; Silver--chemistry; Stereoisomerism; Zirconium--chemistry
PubMed ID:	15673270
Date Deposited:	21 Jan 2014 17:00
Last Modified:	12 Jun 2021 22:56
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/20363

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