Curran, DP and Werner, S
(2004)
Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: Slow addition in a test tube.
Organic Letters, 6 (6).
1021 - 1024.
ISSN 1523-7060
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Abstract
(Equation presented) Partition coefficient measurements and experiments with a dye show that a new fluorous "phase vanishing reaction" described by Jana and Verkade occurs by an extractive mechanism. This mechanism is contrasted with the original diffusive phase-vanishing reactions introduced by Ryu and co-workers.
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Details
| Item Type: |
Article
|
| Status: |
Published |
| Creators/Authors: |
|
| Date: |
18 March 2004 |
| Date Type: |
Publication |
| Journal or Publication Title: |
Organic Letters |
| Volume: |
6 |
| Number: |
6 |
| Page Range: |
1021 - 1024 |
| DOI or Unique Handle: |
10.1021/ol0499248 |
| Schools and Programs: |
Dietrich School of Arts and Sciences > Chemistry |
| Refereed: |
Yes |
| ISSN: |
1523-7060 |
| MeSH Headings: |
Azo Compounds; Countercurrent Distribution; Diffusion; Ethylene Dibromide--chemistry; Fluorocarbons--chemistry; Indicators and Reagents; Methylene Chloride--chemistry; Solvents--chemistry; Time Factors |
| PubMed ID: |
15012090 |
| Date Deposited: |
30 Oct 2013 16:59 |
| Last Modified: |
02 Feb 2019 15:58 |
| URI: |
http://d-scholarship-dev.library.pitt.edu/id/eprint/19909 |
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