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Quasienantiomers and quasiracemates: New tools for identification, analysis, separation, and synthesis of enantiomers

Zhang, Q and Curran, DP (2005) Quasienantiomers and quasiracemates: New tools for identification, analysis, separation, and synthesis of enantiomers. Chemistry - A European Journal, 11 (17). 4866 - 4880. ISSN 0947-6539

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Abstract

The old adage "never mix pure organic compounds" holds in spades for enantiomers. After going to all the trouble to make enantiopure molecules, who in their right mind would ever mix them to make a racemate? Quasienantiomers are almost enantiomers, but not quite. Yet unlike enantiomers, the interest is not so much in separating them but in mixing them to make quasiracemates. This backwards thinking opens new possibilities for identification, analysis, separation and synthesis of enantiomers. A short history is provided, the terms are defined and illustrated, and recent applications of quasienantiomers, quasiracemates and related species are reviewed. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.


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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Zhang, Q
Curran, DPcurran@pitt.eduCURRAN
Date: 19 August 2005
Date Type: Publication
Journal or Publication Title: Chemistry - A European Journal
Volume: 11
Number: 17
Page Range: 4866 - 4880
DOI or Unique Handle: 10.1002/chem.200500076
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0947-6539
MeSH Headings: Catalysis; Hydrolysis; Stereoisomerism
PubMed ID: 15915521
Date Deposited: 22 Jul 2013 17:34
Last Modified: 02 Feb 2019 15:58
URI: http://d-scholarship-dev.library.pitt.edu/id/eprint/19342

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