Tonoi, T and Zhang, W and Curran, DP and Mikami, K
(2008)
Fluorous "racemic" mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds.
Chirality, 20 (3-4).
597 - 603.
ISSN 0899-0042
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Abstract
The proof of concept experiments of fluorous "racemic" mixture synthesis (FRMS) is shown using polysaccharide-based chiral stationary phases. The mixture of racemic O-benzoylmandelate derivatives bearing different lengths of fluorous cleavable tags undergoes sequential reactions to provide individual derivatives as well as their enantiomers resolved on polysaccharide-based chiral HPLC columns (DAICEL CHIRALCEL® and CHIRALPAK® series). © 2008 Wiley-Liss, Inc.
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Details
Item Type: |
Article
|
Status: |
Published |
Creators/Authors: |
Creators | Email | Pitt Username | ORCID ![](/images/orcid_id_24x24.png) |
---|
Tonoi, T | | | | Zhang, W | | | | Curran, DP | curran@pitt.edu | CURRAN | | Mikami, K | | | |
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Date: |
3 March 2008 |
Date Type: |
Publication |
Journal or Publication Title: |
Chirality |
Volume: |
20 |
Number: |
3-4 |
Page Range: |
597 - 603 |
DOI or Unique Handle: |
10.1002/chir.20487 |
Schools and Programs: |
Dietrich School of Arts and Sciences > Chemistry |
Refereed: |
Yes |
ISSN: |
0899-0042 |
MeSH Headings: |
Chromatography, High Pressure Liquid--methods; Fluorine--chemistry; Magnetic Resonance Spectroscopy; Mandelic Acids--chemical synthesis; Mandelic Acids--chemistry; Mandelic Acids--isolation & purification; Polysaccharides; Stereoisomerism |
PubMed ID: |
18205199 |
Date Deposited: |
08 Apr 2013 17:20 |
Last Modified: |
02 Feb 2019 15:58 |
URI: |
http://d-scholarship-dev.library.pitt.edu/id/eprint/18119 |
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