Hammer, NI and Hinde, RJ and Compton, RN and Diri, K and Jordan, KD and Radisic, D and Stokes, ST and Bowen, KH
(2004)
Dipole-bound anions of highly polar molecules: Ethylene carbonate and vinylene carbonate.
Journal of Chemical Physics, 120 (2).
685 - 690.
ISSN 0021-9606
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Abstract
Narrow intense resonances in the photodetachment spectra of the valence-bound anions of several polar molecules were observed. The experiments showed that molecules which support valence-bound anion states may also exhibit features characteristic of dipole-bound anions. This paper considers the diabatic coupling terms between dipole-bound and valence-bound negative ion states of nitromethane.
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