NHC-catalyzed chemo- and regioselective hydrosilylation of carbonyl derivatives

Zhao, Q and Curran, DP and Malacria, M and Fensterbank, L and Goddard, JP and Lacôte, E (2012) NHC-catalyzed chemo- and regioselective hydrosilylation of carbonyl derivatives. Synlett (3). 433 - 437. ISSN 0936-5214

Plain Text (licence) Available under License : See the attached license file. Download (1kB)

Abstract

The hydrosilylation of carbonyl derivatives has been explored by the activation of diphenylsilane in the presence of a catalytic amount of an N-heterocyclic carbene (NHC). Presumably, a hypervalent silicon intermediate featuring strong Lewis acid character allows dual activation of both the carbonyl moiety and the hydride at the silicon center. Reduction under mild conditions could be accomplished using this organocatalytic process. Some interesting selectivities have been encountered. © Georg Thieme Verlag Stuttgart · New York.

---

Share

Citation/Export:	Select format... Citation - Text Citation - HTML Endnote BibTex Dublin Core OpenURL MARC (ISO 2709) METS MODS EP3 XML Reference Manager Refer
Social Networking:	Share |

---

Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Zhao, Q Curran, DP curran@pitt.edu CURRAN Malacria, M Fensterbank, L Goddard, JP Lacôte, E
Date:	27 January 2012
Date Type:	Publication
Journal or Publication Title:	Synlett
Number:	3
Page Range:	433 - 437
DOI or Unique Handle:	10.1055/s-0031-1290208
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0936-5214
Date Deposited:	08 Apr 2013 17:39
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/17995

---

Metrics

Monthly Views for the past 3 years

Plum Analytics

Altmetric.com

---

Actions (login required)

View Item