Robertson, WH and Johnson, MA and Myshakin, EM and Jordan, KD
(2002)
Isolating the charge-transfer component of the anionic H bond via spin suppression of the intracluster proton transfer reaction in the NO<sup>-</sup>·H<inf>2</inf>O entrance channel complex.
Journal of Physical Chemistry A, 106 (42).
10010 - 10014.
ISSN 1089-5639
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Abstract
We report the vibrational predissociation spectrum of the NO-·H2O complex in the OH stretching region. The ionic H-bonded OH stretch is much less red-shifted and less structured in the vibrational spectrum of NO-·H2O than in that of the O2-·H2O cluster, despite the larger proton affinity of NO- relative to O2-. It is argued that the differences between the spectra of these two species are primarily a consequence of the greater charge-transfer character in the O2-·H2O cluster and that the charge-transfer component is much less important in NO-·H2O because of its triplet spin character.
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