The parent borylene: Betwixt and between

Curran, DP and Boussonnière, A and Geib, SJ and Lacôte, E (2012) The parent borylene: Betwixt and between. Angewandte Chemie - International Edition, 51 (7). 1602 - 1605. ISSN 1433-7851

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Abstract

Still elusive: The reduction of dimethylimidazol-2-ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene dichloroborane and the related dimesityl derivative provide novel C-H insertion products that may have arisen from a borylene. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Curran, DP curran@pitt.edu CURRAN Boussonnière, A Geib, SJ geib@pitt.edu GEIB 0000-0002-9160-7857 Lacôte, E
Date:	13 February 2012
Date Type:	Publication
Journal or Publication Title:	Angewandte Chemie - International Edition
Volume:	51
Number:	7
Page Range:	1602 - 1605
DOI or Unique Handle:	10.1002/anie.201107238
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1433-7851
MeSH Headings:	Boron Compounds--chemical synthesis; Boron Compounds--chemistry; Crystallography, X-Ray; Models, Molecular; Molecular Structure
PubMed ID:	22311810
Date Deposited:	29 Mar 2013 16:16
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/17968

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