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Infrared predissociation spectroscopy of I<sup>-</sup>·(CH<inf>3</inf>OH)<inf>n</inf>, n = 1,2: Cooperativity in asymmetric solvation

Robertson, WH and Karapetian, K and Ayotte, P and Jordan, KD and Johnson, MA (2002) Infrared predissociation spectroscopy of I<sup>-</sup>·(CH<inf>3</inf>OH)<inf>n</inf>, n = 1,2: Cooperativity in asymmetric solvation. Journal of Chemical Physics, 116 (12). 4853 - 4857. ISSN 0021-9606

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Abstract

Infrared predissociation spectroscopy of I-·(CH3OH)n was studied. The spectra of the cold, argon-solvated clusters establish the coexistence of two isomeric forms of n=2 cluster, with the asymmetric isomer displaying a dramatic OH red-shift. It was observed that the strongly red-shifted band is suppressed, while the bands assigned to the more open form are enhanced.

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Details

Item Type: Article
Status: Published
Creators/Authors:
CreatorsEmailPitt UsernameORCID
Robertson, WH
Karapetian, K
Ayotte, P
Jordan, KDjordan@pitt.eduJORDAN
Johnson, MA
Date: 22 March 2002
Date Type: Publication
Journal or Publication Title: Journal of Chemical Physics
Volume: 116
Number: 12
Page Range: 4853 - 4857
DOI or Unique Handle: 10.1063/1.1451249
Schools and Programs: Dietrich School of Arts and Sciences > Chemistry
Refereed: Yes
ISSN: 0021-9606
Date Deposited: 29 Mar 2013 16:14
Last Modified: 12 Jun 2021 22:55
URI: http://d-scholarship-dev.library.pitt.edu/id/eprint/17962

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