N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes

Zhao, Q and Curran, DP and Malacria, M and Fensterbank, L and Goddard, JP and Lacôte, E (2011) N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes. Chemistry - A European Journal, 17 (36). 9911 - 9914. ISSN 0947-6539

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Abstract

Reducing alkenes to tears: Addition of structurally diverse N-heterocyclic carbenes (NHCs) to silicon allows the reduction of propargylic and styryl alcohols through an organocatalyzed silylation/direct hydride transfer tandem reaction (see scheme). Catalytic turnover is enabled by the switch to and from hypervalent silicon. This provides a new synthetic application of NHC-main group element complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Zhao, Q Curran, DP curran@pitt.edu CURRAN Malacria, M Fensterbank, L Goddard, JP Lacôte, E
Date:	29 August 2011
Date Type:	Publication
Journal or Publication Title:	Chemistry - A European Journal
Volume:	17
Number:	36
Page Range:	9911 - 9914
DOI or Unique Handle:	10.1002/chem.201101822
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0947-6539
PubMed ID:	21796697
Date Deposited:	14 Mar 2013 14:12
Last Modified:	02 Feb 2019 15:59
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/17714

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