Tehfe, MA and Monot, J and Malacria, M and Fensterbank, L and Fouassier, JP and Curran, DP and Lacôte, E and Lalevée, J
(2012)
A water-compatible NHC-borane: Photopolymerizations in water and rate constants for elementary radical reactions.
ACS Macro Letters, 1 (1).
92 - 95.
![[img]](http://d-scholarship-dev.library.pitt.edu/style/images/fileicons/text_plain.png) |
Plain Text (licence)
Available under License : See the attached license file.
Download (1kB)
|
Abstract
Rate constants for important elementary reactions of 2,4-dimethyl-1,2,4- triazol- 3-ylidene borane (1) and its derived boryl radical have been measured in the presence and absence of water. Reactions including H-abstraction by tBuO, and onward reactions of the derived radical with methyl acrylate (addition), iodopropane (halogen abstraction), and an iodonium salt (oxidation) are unaffected by the presence of a high concentration (1.5 M) of water. Extending these results, borane (1) has been found to be an efficient new co-initiator for the visible light photopolymerization of monomers in the presence of both air and water. © 2011 American Chemical Society.
Share
| Citation/Export: |
|
| Social Networking: |
|
Details
Metrics
Monthly Views for the past 3 years
Plum Analytics
Altmetric.com
Actions (login required)
 |
View Item |
![[feed]](/images/feed-icon-32x32.png){kind=icon}