Chu, Q and Henry, C and Curran, DP
(2008)
Second-generation tags for fluorous chemistry exemplified with a new fluorous Mitsunobu reagent.
Organic Letters, 10 (12).
2453 - 2456.
ISSN 1523-7060
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Abstract
(Chemical Equation Presented) A new fluorous DEAD reagent bearing two perfluoro-tert-butyloxy groups with propylene spacers shows excellent promise for use in fluorous Mitsunobu reactions. Pure target products were obtained in good yields after removing fluorous byproducts by FSPE. The new reagent serves as a prototype for a greener second generation of fluorous reagents bearing tags that are not expected to degrade in the environment to compounds that are highly persistent or that bioaccumulate in higher organisms. © 2008 American Chemical Society.
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Details
Item Type: |
Article
|
Status: |
Published |
Creators/Authors: |
Creators | Email | Pitt Username | ORCID ![](/images/orcid_id_24x24.png) |
---|
Chu, Q | | | | Henry, C | | | | Curran, DP | curran@pitt.edu | CURRAN | |
|
Date: |
1 December 2008 |
Date Type: |
Publication |
Journal or Publication Title: |
Organic Letters |
Volume: |
10 |
Number: |
12 |
Page Range: |
2453 - 2456 |
DOI or Unique Handle: |
10.1021/ol800750q |
Schools and Programs: |
Dietrich School of Arts and Sciences > Chemistry |
Refereed: |
Yes |
ISSN: |
1523-7060 |
MeSH Headings: |
Alkenes--chemistry; Azo Compounds--chemistry; Hydrocarbons, Fluorinated--chemical synthesis; Hydrocarbons, Fluorinated--chemistry; Indicators and Reagents; Models, Molecular; Molecular Structure |
PubMed ID: |
18484733 |
Date Deposited: |
12 Mar 2013 19:35 |
Last Modified: |
02 Feb 2019 15:59 |
URI: |
http://d-scholarship-dev.library.pitt.edu/id/eprint/17662 |
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