Suzuki-miyaura coupling of NHC-Boranes: A new addition to the C-C coupling toolbox

Monot, J and Makhlourbrahmi, M and Ueng, SH and Robert, C and Murr, MDEI and Curran, DP and Malacria, M and Fensterbank, L and Lacôte, E (2009) Suzuki-miyaura coupling of NHC-Boranes: A new addition to the C-C coupling toolbox. Organic Letters, 11 (21). 4914 - 4917. ISSN 1523-7060

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Abstract

Complexes of triaryl- and trialkylboranes with N-heterocyclic carbenes (NHCs) participate In Suzuki-Miyaura cross-coupling reactions and provide coupled products In good yields under base-free conditions. The reaction can be applied to Csp2-Csp2 and Csp2-Csp3 carbon-carbon bond formation with triflates, iodides, bromides, and chlorides. These results enrich the utility of NHC-borane complexes, which can be added to the toolkit of Suzukl-Miyaura cross-couplings, along with boronlc acids and organotrlfluoroborates. © 2009 American Chemical Society.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Monot, J Makhlourbrahmi, M Ueng, SH Robert, C Murr, MDEI Curran, DP curran@pitt.edu CURRAN Malacria, M Fensterbank, L Lacôte, E
Date:	5 November 2009
Date Type:	Publication
Journal or Publication Title:	Organic Letters
Volume:	11
Number:	21
Page Range:	4914 - 4917
DOI or Unique Handle:	10.1021/ol902012c
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1523-7060
PubMed ID:	19799407
Date Deposited:	18 Feb 2013 15:34
Last Modified:	08 Oct 2021 13:55
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/17332

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