Enantioselective -chlorination of aldehydes with recyclable fluorous (s)-pyrrolidine-thiourea bifunctional organocatalyst

Wang, L and Cai, C and Curran, DP and Zhang, W (2010) Enantioselective -chlorination of aldehydes with recyclable fluorous (s)-pyrrolidine-thiourea bifunctional organocatalyst. Synlett (3). 433 - 436. ISSN 0936-5214

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Abstract

A novel fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst is prepared. The catalyst shows good activity and enantioselectivity for direct -chlorination of aldehydes using N-chlorosuccinimide (NCS) as the chlorine source. It can be recovered from the reaction mixture by fluorous solid-phase extraction with excellent purity for direct reuse. © Georg Thieme Verlag Stuttgart · New York.

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Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Wang, L Cai, C Curran, DP curran@pitt.edu CURRAN Zhang, W
Date:	15 February 2010
Date Type:	Publication
Journal or Publication Title:	Synlett
Number:	3
Page Range:	433 - 436
DOI or Unique Handle:	10.1055/s-0029-1219198
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	0936-5214
PubMed Central ID:	PMC2922060
PubMed ID:	20717504
Date Deposited:	14 Feb 2013 21:15
Last Modified:	01 Mar 2019 14:55
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/17323

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