Generation and reactions of an unsubstituted n-heterocyclic carbene boryl anion

Monot, J and Solovyev, A and Bonin-Dubarle, H and Derat, E and Curran, DP and Robert, M and Fensterbank, L and Malacria, M and Lacôte, E (2010) Generation and reactions of an unsubstituted n-heterocyclic carbene boryl anion. Angewandte Chemie - International Edition, 49 (48). 9166 - 9169. ISSN 1433-7851

Plain Text (licence) Available under License : See the attached license file. Download (1kB)

Abstract

Lying low: A lithiated unsubstituted N-heterocyclic carbene (NHC) boryl anion can be generated by reduction, and trapped by electrophiles (see scheme; dipp=2,6-diisopropylphenyl) to provide new substituted NHC boranes. It is yet another example of a low-valent boron compound or boron-containing reactive intermediate stabilized by an NHC, thereby extending the scope of NHC borane chemistry. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

---

Share

Citation/Export:	Select format... Citation - Text Citation - HTML Endnote BibTex Dublin Core OpenURL MARC (ISO 2709) METS MODS EP3 XML Reference Manager Refer
Social Networking:	Share |

---

Details

Item Type:	Article
Status:	Published
Creators/Authors:	Creators Email Pitt Username ORCID Monot, J Solovyev, A Bonin-Dubarle, H Derat, E Curran, DP curran@pitt.edu CURRAN Robert, M Fensterbank, L Malacria, M Lacôte, E
Date:	22 November 2010
Date Type:	Publication
Journal or Publication Title:	Angewandte Chemie - International Edition
Volume:	49
Number:	48
Page Range:	9166 - 9169
DOI or Unique Handle:	10.1002/anie.201004215
Schools and Programs:	Dietrich School of Arts and Sciences > Chemistry
Refereed:	Yes
ISSN:	1433-7851
PubMed ID:	20853388
Date Deposited:	08 Feb 2013 21:09
Last Modified:	02 Feb 2019 15:58
URI:	http://d-scholarship-dev.library.pitt.edu/id/eprint/17237

---

Metrics

Monthly Views for the past 3 years

Plum Analytics

Altmetric.com

---

Actions (login required)

View Item