Clarkson, JR and Dian, BC and Moriggi, L and Defusco, A and McCarthy, V and Jordan, KD and Zwier, TS
(2005)
Direct measurement of the energy thresholds to conformational isomerization in Tryptamine: Experiment and theory.
Journal of Chemical Physics, 122 (21).
ISSN 0021-9606
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Abstract
The methods of stimulated emission pumping-hole spectroscopy (SEP-HFS) and stimulated emission pumping population transfer spectroscopy (SEP-PTS) were applied to the conformation-specific study of conformational isomerization in tryptamine. The methods employ stimulated emission pumping to selectively excite a fraction of the population of a single conformation of TRA to well-defined ground-state vibration levels. The method uses collisions as an integral part of the experimental scheme. Hole-filling methods can also be applied to the study of isomerization in a much wider range of contexts.
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